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Development
of cathodes for SOFCs
Solid Oxide Fuel Cells (SOFC) are attractive for a wide range of applications,
from battery replacements, to automotive auxiliary power units, to large-scale
electrical power generation. In SOFCs, oxygen anions are transported through
an oxide membrane and react with the fuel at the anode (Figure). One of
the most important subjects in the development of SOFCs is the improvement
of the electrode performance to avoid severe limitations on the operating
conditions and large efficiency losses. A wide number of perovskitic materials
have been investigated with the aim to improve the performance of the
cathode. Our work involves the preparation and the complete characterization
(structural, morphological and electrochemical properties) of new cathode
materials for intermediate - temperature SOFCs (IT - SOFCs).
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Selected
publications
1. S. Lee, M. Bevilacqua, P. Fornasiero, J. M. Vohs and R. J. Gorte, SOFC
Cathodes Prepared by Infiltration of LNF and LSNF in Porous YSZ.,
Journal of Power Sources 193 (2009), 747-753, doi:10.1016/j.jpowsour.2009.04.046.
2. T. Montini, M. Bevilacqua, E. Fonda, M. F. Casula, S. Lee, C. Tavagnacco,
R. J. Gorte and P. Fornasiero, Relationship between electrical behavior
and structural characteristics in Sr-doped LaNi0.6Fe0.4O3-d
mixed oxides., Chemistry of Materials 21 (2009), 1768-1774,
doi:10.1021/cm900467c.
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