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Recent
Publications
“Routes
to the preparation of mixed monolayers of fluorinated and hydrogenated
alkanetiolates grafted on the surface of gold nanoparticles”. M.
Şologan, C. Cantarutti, S. Bidoggia, S. Polizzi, P. Pengo, L. Pasquato Faraday Discussion 2016, DOI: 10.1039/C6FD00016A.
“The dual role of a pre-organized scaffold presenting four
residues of a GM-3 lactone mimetic on melanoma modulation”. B.
Richichi, G. Comito, O. Renaudet, M. Fiore, A. Marra, B. Stecca, L.
Pasquato, P. Chiarugi, C. Nativi ACS Med. Chem. Lett. 2016, 7, 28-33.
“Gold Nanoparticles Protected by Fluorinated Ligands: Syntheses,
Properties and Applications”. P. Pengo, L. Pasquato, J. Fluorine Chemistry, 2015, 177, 2-10.
"Differential reactivity of the inner and outer positions of
Au25(SCH2CH2Ph)18 dimeric staples under place exchange
conditions”. P. Pengo, C. Bazzo, M. Boccalon, L. Pasquato, Chem. Commun. 2015, 51, 3204 – 3207.
“Gold nanoparticles as drug carriers: a contribution to the quest
of basic principles for monolayer design”. M. Boccalon, S.
Bidoggia, F. Romano, L. Gualandi, P. Franchi, M. Lucarini, P. Pengo, L.
Pasquato, J. Mater. Chem. B. 2015, 3, 432 – 439.
“Physico-Chemical
Characteristics of Gold Nanoparticles” V. Amendola, M.
Meneghetti, M. Stener, Y. Guo, S. Chen, P. Crespo, M. A. García,
A. Hernando, P. Pengo, L. Pasquato in Gold Nanoparticles in Analytical
Chemistry, Comprehensive Analytical Chemistry, Eds. M. Valcarcel, A. I.
Lopez-Lorente, Volume 66, 2014, Pages 81-152.
“Gold
nanoparticles protected by fluorinated ligands for 19F MRI”. M.
Boccalon, P. Franchi, M. Lucarini, J. J. Delgado, F. Sousa, F.
Stellacci, I. Zucca, A. Scotti, R. Spreafico, P. Pengo, L. Pasquato, Chem. Commun. 2013, 49, 8794-8796.
“Multivalent
Presentation of a Hydrolytically Stable GM3 Lactone Mimetic as
Modulator of Melanoma Cells Motility and Adhesion”. B. Richichi,
G. Comito, L. Cerofolini, G. Gabrielli, A. Marra, L. Moni, A. Pace, L.
Pasquato, P. Chiarugi, A. Dondoni, L. Toma, C. Nativi, Bioor. Med. Chem. 2013, 21, 2756-2763.
"Self-organization
of mixtures of fluorocarbon- and hydrocarbon amphiphilic thiolates on
the surface of gold nanoparticles”. P. Posocco, C. Gentilini, S.
Bidoggia, A. Pace, P. Franchi, M. Lucarini, M. Fermeglia, S. Pricl, L.
Pasquato, ACS Nano 2012, 6, 7243-7253.
"Active
and stable embedded Au@CeO2 catalysts for preferential oxidation of
CO". M. Cargnello, C. Gentilini, T. Montini, F. Fonda, S. Mehraeen, M.
Chi, M. Herrera-Collado, N. D. Browning, L. Pasquato, P. Fornasiero, Chem. Mater. 2010, 22, 4335-4345.
"ESR
spectroscopy as a tool to investigate the properties of self-assembled
monolayers protecting metal nanoparticles". M. Lucarini, L. Pasquato,
Nanoscale, 2010, 668-676.
"Modified
gold nanoparticles and surfaces". P. Pengo, L. Pasquato in
Supramolecular chemistry of organic-inorganic hybrid material; K,
Rurack, R. Martinez-Manez Eds., Wiley, New York, 2010.
"Morphology of mixed-monolayers protecting metal nanoparticles". C. Gentilini, L. Pasquato, J. Mater. Chem. 2010, 20, 1403-1412.
"Formation
of patches on 3D-SAMs driven by thiols with immiscible chains
revealed by ESR spectroscopy". C. Gentilini, P. Franchi, E.
Mileo, S. Polizzi, M. Lucarini, L. Pasquato, Angew. Chem. 2009,
48, 3060-3064.
"Water-soluble
Gold Nanoparticles Protected by Fluorinated Amphiphilic Thiolates".
C. Gentilini, F. Evangelista, P. Rudolf, P. Franchi, M. Lucarini,
L. Pasquato, J. Am. Chem. Soc. 2008, 130,
15678-15682.
"Straightforward
Synthesis of Fluorinated Amphiphilic Thiols". C. Gentilini, M.
Boccalon, L. Pasquato, Eur. J. Org. Chem. 2008,
3308-3313.
"Mechanistic
investigation on 2-aza-spiro[4,5]decan-3-one formation from 1-(aminomethyl)cycloehylacetic
acid (gabapentin)". E. Zambon, R. Giovanetti, L. Cotarca, L.
Pasquato, Tetrahedron, 2008, 64, 6739-6743.
"Cooperative
Nanosystems". C. Guarise, F. Manea, G. Zaupa, L. Pasquato, L.
J. Prins, P. Scrimin, J. Pep. Sci. 2008, 14,
174-183.
"Multivalent
Catalysts for the cleavage of Nucleic Acids and their Models".
F. Manea, L. Pasquato, L. J. Prins, P. Scrimin, Nucleic Acids Symposium Series 2004, 2007, 52, 67-68.
"
Metallodendrimers as Transphosphorilation Catalysts". M.
Martin, F. Manea, R. Fiammengo, L. J. Prins, L. Pasquato, P. Scrimin, J.
Am. Chem. Soc. 2007,
129, 6982-6983.
"Decorating
carbon nanotubes with metal or semiconductor nanoparticles". V.
Georgakilas, D. Gournis, V. Tzitzios, L. Pasquato, D. M. Guldi, M.
Prato, J. Mater. Chem. 2007,
17, 2679-2694.
"Monolayer
protected gold nanoparticles on ceria for an efficient CO
oxidation catalyst". N.
Hickey, P. A. Larochette, C. Gentilini, L. Sordelli, L.
Olivi, S. Polizzi, T. Montini, P. Fornasiero, L. Pasquato, M.
Graziani, Chem. Mater., 2007,
19, 650-651.
"Solvent
polarity controls the Helical Conformation
of Short Peptides Rich in Ca-tetrasubstituted
amino acids". M.
Bellanda, S. Mammi, S. Geremia, N. Demitri, L. Randaccio, Q. B.
Broxterman, B. Kaptein, P. Pengo, L. Pasquato, P. Scrimin, Chem.
Eur. J. 2007, 13,
407-416.
"Substrate
modulation of the activity of an artificial esterase made of
peptide-funtionalized gold nanoparticles". P. Pengo, L.
Baltzer, L. Pasquato, P. Scrimin, Angew.
Chem. Int. Ed. 2007,
46, 400-404.
"La
reazione di metatesi: una reazione da Nobel", L. Pasquato, AIM Magazine, 2006, 61,
48-54.
"Gold
nanoparticles-based protease assay". C. Guarise, L. Pasquato,
V. De Filippis, P. Scrimin, Proc.
Natl. Acad. Sci. U.S.A., 2006,
103, 3978-3982.
"Effect
of core size on the partition of organic solutes in the monolayer
of water soluble nanoparticles: an ESR investigation". M.
Lucarini, P. Franchi, G. F. Pedulli, C. Gentilini, S. Polizzi, P.
Pengo, P. Scrimin, L. Pasquato, J. Am. Chem. Soc., 2005, 127, 16384-16385.
"Dispersable
Carbon Nanotubes / Gold Nanohybrids: Evidence for Strong
Electronic Interactions". G.M.A.
Rahman, D. M. Guldi, E. Zambon, L. Pasquato, N. Tagmatarchis, M.
Prato, Small, 2005,
1, 527-530.
“Reversible
aggregation/disaggregation of gold nanoparticles induced by a
cleavable dithiol linker”. C.
Guarise, L. Pasquato, P. Scrimin, Langmuir,
2005, 21,
5537-5541.
"Carboxylate-Imidazole
Cooperativity in Dipeptide-functionalized Gold Nanoparticles with
Esterase-like Activity". P.
Pengo, S. Polizzi, L. Pasquato, P. Scrimin, J.
Am. Chem.
Soc.
2005, 127,
1616-1617.
"Nanozymes:
Functional Nanoparticles-based Catalysts". L.
Pasquato, P. Pengo, P. Scrimin, Supramol.
Chem.,
2005, 17,
163-171.
"Functional
Gold Nanoparticles for Recognition and Catalysis". L.
Pasquato, P. Pengo, P. Scrimin, J.
Mater. Chem., 2004,
14,
3481-3487.
"Nanozymes:
Gold-nanoparticles-based Transphosphorylation Catalysts". F.
Manea, F. Bodar Houillon, L. Pasquato, P. Scrimin, Angew.
Chem. Int. Ed., 2004,
43, 6165-6169.
"EPR
Study of Dialkyl Nitroxides as Probes to Investigate the Exchange
of Solutes between the Ligand Shell of Monolayersof Protected Gold
Nanoparticles and Aqueous Solutions" M. Lucarini, P. Franchi,
G. F. Pedulli, P. Pengo, P. Scrimin, L. Pasquato, J.
Am. Chem. Soc., 2004,
126, 9326-9329.
“Role
of Secondary Structure in the Asymmetric Acylation Reaction
Catalyzed by Peptides Based on Chiral Ca-Tetrasubstituted
a-Amino
Acids”. F. Formaggio,
A. Barazza, A. Bertocco, C. Toniolo, Q. B. Broxterman, B. Kaptein,
E. Brasola, P. Pengo, L. Pasquato, P. Scrimin, J.
Org. Chem.
2004, 69,
3849-3856.
TOP
"Synthesis,
characterization and properties of water-soluble gold
nanoparticles with tunable core size". P.
Pengo, S. Polizzi, M. Battagliarin, L. Pasquato, P.
Scrimin, J. Mater. Chem.
2003, 2471-2478.
"Enzyme-mimicking
activity in a nanoparticle". L. Pasquato, P. Pengo, Specialty
Chemicals Magazine, September 2003, 38-40.
"C2-symmetrical
sterol-polyether conjugates as highly efficient synthetic
ionophores". E.
Avallone, I. Izzo, G. Vuolo, M. Costabile, D. Garrisi, L. Pasquato,
P. Scrimin, P. Tecilla, F. De Riccardis, Tetrahedron Lett. 2003,
44, 6121-6124.
"Nucleophilic
Reactions at the Ring Carbons of Thiiranium and Thiirenium Ions.
An Experimental and Theoretical Comparison of the SN2
and SN2-Vin Mechanisms". G.
Borsato, V. Lucchini, G. Modena, L. Pasquato, A. Zambon, ARKIVOC
2003, (xiii), 38-55.
"Quantitative
Correlation of Solvent Polarity with the 310-/a-Helix
Equilibrium: a Heptapeptide Behaves as a Solvent-Driven Molecular
Spring". P. Pengo,
L. Pasquato, S. Moro, A. Brigo, F. Fogolari, Q. B. Broxterman, B.
Kaptein, P. Scrimin, Angew. Chem.
Int. Ed.
2003, 42, 3388-3392.
“Multivalent
recognition of bis- and tris-Zn-porphyrins by N-methylimidazole
functionalized gold nanoparticles”. G.
Fantuzzi, P. Pengo, R. Gomilla, P. Ballester, C. A. Hunter, L.
Pasquato, P. Scrimin, Chem. Commun.
2003, 1004-1005.
Biological
and Biomimetic Applications of Nanoparticles. L. Pasquato, P.
Pengo, P. Scrimin in “Nanoparticles: Building Blocks for
Nanotecnology”, Ed. V. M. Rotello, Kluwer, Ch. 10, 2003,
p.251-282.
“Synthesis
of a Stable Helical Peptide and Grafting on Gold Nanoparticles”.
P. Pengo, Q. B. Broxterman, B. Kaptein, L. Pasquato, P. Scrimin, Langmuir,
2003, 19, 2521-2524.
“Recent
advances in stereoselective functionalisation of olefins via
thiiranium ion intermediates”. L.
Pasquato, Specialty Chemicals Magazine, Dicembre 2002,
21-24.
"Gold
Nanoparticles Protected with Triethyleneglycol-functionalized
Thiolates: Acid Induced Clustering of the Aggregates and Solvent
Dependent Optical Properties". P.
Pengo, G. Fantuzzi, L. Pasquato, P. Scrimin J. Supramol. Chem.
2002, 2, 305-310.
TOP
“An
artificial ionophore based on a polyhydroxylated steroid dimer”.
M. Di Filippo, D.
Garrisi, I. Izzo, F. Mancin, L. Pasquato, F. De Riccardis, P.
Scrimin, P. Tecilla, Chem. Commun.
2002, 3066-3067.
“NMR
Enantiodifferentiation of thiiranium cations by chiral
hexacoordinated phosphate anions”. L. Pasquato, C. Herse, J.
Lacour, Tetrahedron Lett. 2002, 43,
5517-5520.
“Electrophilic
Additions to Carbon-Carbon Double Bonds: Synthetic and Mechanistic
Aspects”. L. Pasquato,
Seminars in Organic Synthesis, 2002, Società Chimica Italiana, pp
87-109.
“Duality
of Mechanism in the Tetramethylfluoroformamidinium
Hexaphluorophosphate (TFFH) Mediated Z-aminoacid Fluorides
Synthesis”. R.
Fiammengo, G. Licini, A. Nicotra, G. Modena, L. Pasquato, P.
Scrimin, Q. B. Broxterman, B. Kaptain, J.
Org. Chem.,
2001, 66,
5905.
“RS+”as
Coupling Reagent for Phosphorylation and Carboxylic Acid
Activation”. L.
Pasquato, G. Santoni and G. Modena, Eur.
J. Org. Chem.,
2001, 3457.
“Geometry
and Conformation of Thietanium Ions from Diffraction Data and Ab
Initio Calculations”. R.
Destro, E. Ortoleva, G. Modena, L. Pasquato, V. Lucchini, Helv.
Chim.
Acta,
2001, 84,
860.
“Conversion
of Bis(trichloromethyl)carbonate to Phosgene and Reactivity of
Triphosgene, Diphosgene and Phosgene with Methanol”. L.
Pasquato, G. Modena, L. Cotarca, P. Delogu, S. Mantovani, J.
Org. Chem.,
2000, 65,
8224.
“N-Methylimidazole-functionalized
gold nanoparticles as catalysts of the cleavage of a carboxylic
acid ester”. L.
Pasquato, F. Rancan, P. Scrimin, F. Mancin, C. Frigeri, Chem.
Commun.,
2000, 2253.
“X-Ray
Structures and Anionotropic Rearrangements of Di-tert-butyl-Substituted
thiiranium and Thiirenium Ions. A Structure-Reactivity
Relationship”. R.
Destro, V. Lucchini, G. Modena, L. Pasquato, J.
Org. Chem.,
2000, 65,
3367.
“Different
Approaching Directions of s
and p
Nucleophiles to the Sulfur Atom of Thiiranium and Thiirenium Ions”.
G. Modena, L. Pasquato,
V. Lucchini, Chem. Eur. J.,
2000, 6,
589.
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